Optimizing for PVP and PVE

Theories

I feel like I have a decent amount of stuff on the game but just not making the most of it. I was hoping you guys could help me optimize my PVP and PVE set up's. Character wise I'm sitting at

Sexy.Yoru / Shini Urahara / Gin / Retsu / Sajin / Pantera Grim / Ikkaku / Dark Rukia / Full Mod Kisuke / Full Mod Rukia / Support Yoru / Kenpachi/Support Toshiro Base. Zan Wise I have all the free ones leveled up plus Sogyo.

Also have around 16 level 5 Fury Stones so I can manage T1 Fury with Kisuke. Will have four more tomorrow, so 20 total.
My current PVP goes Gin > Main > Sexy > Retsu > Sajin. Now my server has a decent amount of T1 Kisuke team's so it's making me second guess my set up even more. What would you guys change? Would you swap Gin for Kisuke then try to just blow them all up with 10 skill? Or should I go for Kisuke + Shini Urahara to control their back line to prevent their T1 Fury?

PVE I feel I screw up the most order wise but team wise I feel is solid with Kisuke > Sexy > Main > Ikkaku > D.Rukia with Sogyo.

Now according to Yagami post from another thread I should go Kisuke > D Rukia > Main 8th Skill > Sexy > Ikkaku. Correct me if I'm wrong.

Now also I was considering buying Shini.Yoru to strengthen my PVP team but if you guys feel she wouldn't add much I might skip over. Since Reio is going on now, be best time to grab her. I'm also working towards Ulq from SWP.

PAOFUI

hmmmm.. for PVE...

maybe u can try... Shini Hara... Dark Rukia ... Ikka ... SEXY Yorui.... with sk8 n also Sogyo...

n see...

ardeof

Kisuke and Dark Rukia before other chars makes sense because that's basically a 1 turn 100% fury for nearly the whole team, which would help ikkaku get his steamroll going.
Edit: The only way D. Rukia last would make sense is if all your other chars can 1 turn fury (ignoring vanguard, of course), then Dark Rukia last would be logical because that'd help with the chars achieving 2nd turn skill again, which would mean kisuke would have to go last/2nd last as well.

Either way you go about playing those characters is up to you.

Theories

Yeah I'll be adjusting the speed for PVE to have Kisuke > D.Rukia > 8th Skill rotation for Ryoka.

Any suggestions on the PVP aspect or Shini Yoru? People have her on my server but none use her lol.