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Sōsuke Aizen (藍染 惣右介, Aizen Sōsuke) is the former captain of the 5th Division in the Gotei 13. He later leaves Soul Society with his followers, Gin Ichimaru and Kaname Tōsen. His lieutenant was Momo Hinamori. After waging war against Soul Society with an army of Arrancar, Aizen was defeated by Ichigo Kurosaki and sealed away by Kisuke Urahara, and then imprisoned for his crimes.
Gin Ichimaru (市丸 ギン, Ichimaru Gin) was the captain of the 3rd Division of the Gotei 13 until he betrayed Soul Society, alongside Sōsuke Aizen and Kaname Tōsen. His lieutenant was Izuru Kira.
Kaname Tōsen (東仙 要, Tōsen Kaname) was the captain of the 9th Division of the Gotei 13 until he betrayed Soul Society, alongside Sōsuke Aizen and Gin Ichimaru. This betrayal put him at odds with his former best friend Sajin Komamura, as well as his former lieutenant in the 9th Division, Shūhei Hisagi.
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